Problem Set #3 (Due Tuesday, September 12, 2000 @ Dr.
Gelder's Office by 4:30 p.m.) : Answers : Grading
Info
Sample problem like PS4.1 and 4.2
from lecture on Wednesday, September 13, 2000.
Sample problem like PS4.5 from
Help Session on Wednesday, September 20, 2000.
Sample problem PS4.6d from Help
Session on Wednesday, September 20, 2000.
Sample problem like PS4.10 from
Help Session on Wednesday, September 20, 2000.
Here are the two limiting reagent problems I did in class on Wednesday,
September 20th. The first is the combustion
of ethane problem and the second is the reaction between calcium
and nitrogen problem. If you are having trouble with PS4.7 - PS4.10 these
sample problems may help.
Problem Set #5 (Due Wednesday, September 13, 2000: Section
2, 1:30 - 2:20 pm only) : Answers : Grading Info
(Note: Section 3, 3:30 - 4:20 pm will do a PS5 sometime later.)
Here is some help on combustion
reactions for PS6.1 from lecture on Friday, September 15, 2000.
Here is some help on formation
reactions for PS6.1 from lecture on Friday, September 15, 2000.
Here is some help for PS6.4a from
lecture on Friday, September 22, 2000.
Here is some help for PS6.4b from
lecture on Friday, September 22, 2000.
Sample problem like PS6.5 - PS6.8
from the 1:30 pm lecture on Friday, September 22, 2000.
Sample problem like PS6.5 - PS6.8
from 3:30 pm lecture on Friday, September 22, 2000.
Sample problem like PS6.9 from lecture
on Friday, September 22, 2000.
Here is discussion on using PS7.2 from
the Help Session on Wednesday, October 4, 2000.
Here is discussion and examples on using
the Solubility Table like PS7.3 from the Help Session on Wednesday, October
4, 2000.
Here is an example of a problem like PS8.3
from the Help Session on Wednesday, October 11, 2000.
Here is an example of a problem like
PS8.6 from the Help Session on Wednesday, October 11, 2000.
Here is an example of a problem like PS8.7
from the Help Session on Wednesday, October 11, 2000.
Here is some discussion on PS8.8 from
the Help Session on Wednesday, October 11, 2000.
Here is an example of a problem like PS8.9
from the Help Session on Wednesday, October 11, 2000.
Here is some discussion on PS8.10 from
the Help Session on Wednesday, October 11, 2000.
Here is an example of a problem
like PS9.1 and PS9.2 from the Lecture on Wednesday, October 11, 2000.
Here is an example of a problem like
PS9.3 from the Help Session on Wednesday, October 11, 2000.
Here
is an example of a problem like PS9.4 from the Help Session on Wednesday,
October 11, 2000.
Here is an example of a problem like PS9.6
from Lecture on Friday, October 13, 2000.
Here is an example of a problem like
PS9.6 from Help Session on Sunday, October 15, 2000.
Here is the explanation to PS9.7 from
Help Session on Sunday, October 15, 2000.
Here is an explanation in terms of the
Kinetic Molecular theory of how the pressure of a gas changes with a change
in mol of gas. PS9.8 asks a similar question only in terms of pressure
and volume (from Lecture on Friday, October 13, 2000).
Here is the explanation to PS9.8 from
Lecture on Friday, October 13, 2000.
Here is the explanation to PS9.8 from
Help Session on Sunday, October 15, 2000.
Here is an explanation in terms of the
Kinetic Molecular theory of how the pressure of a gas changes with a change
in temperature of the gas. PS9.8 asks a similar question only in terms
of pressure and volume (from Lecture on Friday, October 13, 2000).
Here is the explanation to PS9.9 from
the Help Session on Sunday, October 15, 2000.
Problem Set #10 (Due Wednesday, October 25, 2000))
: Answers : Grading Info
Here is discussion which should help
in PS10.2 from the Help Session on Monday, October 23, 2000.
Here is an example of a problem like
PS10.4 from the Lecture on Wednesday, October 18, 2000.
Here is discussion which should
help in PS10.5 and PS10.6 from lecture on Friday, October 20, 2000.
Here is an example of a problem
like PS10.5 and 10.6 from the Help Session on Monday, October 23, 2000. (Note:
Since we were not in PS141 the audio is a little low, so listen carefully.)
Here is an example of a problem
like PS10.7 and 10.8 from the Help Session on Monday, October 23, 2000. (Note:
Since we were not in PS141 the audio is a little low, so listen carefully.)
Here is an example of a problem like
PS10.9 from the Lecture on Friday, October 20, 2000.
Here is an example of a problem like
PS10.9 from the Help Session on Monday, October 23, 2000.
Here is an second example of a problem
like PS10.9 from the Lecture on Friday, October 20, 2000. (I did not do this
example in the 1:30 pm lecture section.)
Here is an example of a problem like
PS10.10 from the Lecture on Friday, October 20, 2000. (I did not do this example
in the 3:30 pm lecture section.)
Problem Set #11 (Due Wednesday, November 1, 2000) :
Answers : Grading Info
Here is a sample problem similar to PS11.2
that we did in lecture on Friday, October 27, 2000.
Here is a sample problem similar to PS11.3
that we did in the Help Session on Monday, October 30, 2000.
Here are some comments
about PS11.4 and 11.5 from lecture on Wednesday, October 25, 2000.
Here is the first sample problem
using Hess' Law (PS11.4 and PS11.5) that we did on Wednesday, October 25,
2000.
Here is the second sample problem
using Hess' Law that we did on Wednesday, October 25, 2000.
Here is the third sample problem
using Hess' Law (PS11.4 and PS11.5) that we did on Wednesday, October 25,
2000.
Here is the fourth sample problem
using Hess' Law (PS11.4 and PS11.5) that we did in the Help Session on Monday,
October 30, 2000. This one is a little more challenging.
Here is a sample problem using
the approach recommended for PS11.6 we discussed on Wednesday, October 25,
2000.
Here is a second sample problem
using the approach recommended for PS11.6 we discussed on Friday, October
27, 2000.
Here is a third sample problem
using the approach recommended for PS11.6 we discussed on Friday, October
27, 2000.
Here is a sample problem like PS11.7
we discussed on Friday, October 27, 2000.
Here is a second sample problem like
PS11.7 from the Help Session on Monday, October 30, 2000.
Here are some comments about PS11.8 from
the Help Session on Monday, October 30, 2000.
Here is a sample problem like PS11.9
we discussed the in the Help Session on Monday, October 30, 2000.
Problem Set #12 (Due Wednesday, November 8, 2000) :
Answers : Grading Info
Here is a sample problem similar to
PS12.2 that we did in the Help Session on Monday, November 6, 2000.
Here is some discussion on PS12.4 from
the Help Session on Monday, November 6, 2000.
Here is some discussion on PS12.5 from
the Help Session on Monday, November 6, 2000.
Here is some discussion on
PS12.6 from the Help Session on Monday, November 6, 2000.
Here is a sample problem similar to
PS12.6 that we did in the Help Session on Monday, November 6, 2000.
Here is some discussion on
PS12.7 from the Help Session on Monday, November 6, 2000.
Here is some discussion on
PS12.8 from the Help Session on Monday, November 6, 2000.
Here is a sample problem similar to
PS12.8 that we did in the Help Session on Monday, November 6, 2000.
Here is a sample problem similar to
PS12.9 that we did in the Help Session on Monday, November 6, 2000.
Here is a comment about reporting
the answer to PS12.9.
Here is a comment about doing
the math in PS12.9.
Here is a very important comment
about the ideas covered in PS12.9.
Here is some discussion on
PS12.10 from the Help Session on Monday, November 6, 2000.
Here is a comment about the electromagnetic
spectrum and future exams.
Problem Set #13 (Due Monday, November 13, 2000) : Answers
: Grading Info
Here is the discussion that should
help doing PS13.3 from Help Session on Sunday, November 13, 2000.
Here is the discussion that should
help doing PS13.4 from Help Session on Sunday, November 13, 2000.
Here is the discussion that should
help doing PS13.5 from lecture on Friday, November 11, 2000.
Here is some discussion that should
help PS13.5 from the Help Session on Sunday, November 12, 2000.
Here is a problem similar PS13.6 from
the Help Session on Sunday, November 12, 2000.
Here is some discussion and a problem
similar PS13.8 from the Help Session on Sunday, November 12, 2000.
Here is some discussion on PS13.9
from the Help Session on Sunday, November 12, 2000. Check out the lecture
notes for Monday, they may be useful also for PS13.9 and PS13.10.
Here is the discussion introducing
the three quantum numbers; n, l and ml from lecture on Monday,
November 6, 2000. This discussion is important for PS13.2 and PS13.3.
Here is the discussion showing
the three quantum numbers (n, l and ml) for an electron in the
first level from lecture on Monday, November 6, 2000.
Here is the discussion showing
the three quantum numbers (n, l and ml) for an electron in the
second level from lecture on Monday, November 6, 2000.
Here is the discussion showing
the three quantum numbers (n, l and ml) for an electron in the
third level from lecture on Monday, November 6, 2000.
Here is the discussion showing
the boundary surface for the 1s and 2s-orbital from lecture on Monday, November
6, 2000.
Here is the discussion showing
the boundary surface for the three 2p-orbitals from lecture on Monday, November
6, 2000.
Here is the discussion showing
the boundary surface for the five 3d-orbitals from lecture on Monday, November
6, 2000.
Here is the discussion on writing
the set of four quantum numbers, writing the electron configuration and writing
the orbital diagram for hydrogen from lecture on Friday, November 11, 2000.
Here is the discussion on where
the second electron in helium is located and writing the electron configuration
and orbital diagram for helium from lecture on Friday, November 11, 2000.
Here is the discussion on where
the third electron in lithium is located and writing the electron configuration
and orbital diagram for litium from lecture on Friday, November 11, 2000.
Here is the discussion on where
the fourth electron in beryllium is located and writing the electron configuration
and orbital diagram for beryllium from lecture on Friday, November 11, 2000.
Here is the discussion on writing
the electron configuration and orbital diagram for boron from lecture on Friday,
November 11, 2000.
Here is the discussion on writing
the electron configuration and orbital diagram for carbon from lecture on
Friday, November 11, 2000.
Here is the discussion on writing
the electron configuration and orbital diagram for nitrogen, oxygen, fluorine
and neon from lecture on Friday, November 11, 2000.
Here
is the discussion on writing the electron configuration and orbital
diagram for sodium and magnesium from lecture on Friday, November 11, 2000.
Here is the discussion on writing
the electron configuration for an element using the periodic table from
lecture on Friday, November 11, 2000.
Here is the discussion on
writing the electron configuration for aluminum to calcium from lecture
on Friday, November 11, 2000.
Here is the discussion on writing
the electron configuration for the elements scandium through zinc (the first
transition metal series) from lecture on Friday, November 11, 2000.
Here is the discussion on
writing the electron configuration for ions from lecture on Friday, November
11, 2000.
Problem Set #14 (Due Wednesday, November 29, 2000)
: Answers : Grading Info
Here is some discussion and help on
PS14.1 from the Help Session on Monday, November 27, 2000
Here is some discussion and help on
PS14.3a and PS14.3b from the Help Session on Monday, November 27, 2000. (Note:
Check lecture notes on Monday,
November 13, 2000 for an explanation for PS14.3c.)
Here is some discussion and help on
PS14.6 (lattice energy) from the Help Session on Monday, November 27, 2000.
(Note: The tape ran out as I was completing this problem, so check the lecture
notes from Monday, November 13,
2000. There is a discussion of lattice energy and there is a MacroMedia
Director animation that shows the trend for the compounds listed in this problem.
You'll need the Shockwave Plug-in to view the animation.)
Here is some discussion and help on
PS14.7b from the Help Session on Monday, November 27, 2000
Here is some discussion and help on
PS14.9 from the Help Session on Monday, November 27, 2000
Here is some discussion and help on
PS14.10 from the Help Session on Monday, November 27, 2000
Problem Set #15 (Tentatively Due Thursday, November
30, 2000) : Answers : Grading Info
Here is some discussion and help on
PS15.1 from the Help Session on Monday, November 27, 2000. (Note it may also
be useful to look at the clip for PS14.9
and look at the lecture notes
on the Born Haber cycle that I have put up.)
Here is some discussion and help on
PS15.3 from the Help Session on Monday, November 27, 2000. (Note: Here is
a clip from lecture on Wednesday,
November 22, 2000 where I introduce the concept of polar covalent bonds and
nonpolar covalent bonds.)
Here is some discussion and help on
PS15.4 from the Help Session on Monday, November 27, 2000.
Here is some discussion and help on
PS15.5 from the Help Session on Monday, November 27, 2000. (Note: This problem
is similar to a problem we did in PS12.)
Here is an introduction to Lewis structures
from class on Monday, November 27, 2000.
Here is an introduction to figuring
out a skeletal structure from class on Monday, November 27, 2000.
Here is the Lewis structrue for CCl4
from class on Monday, November 27, 2000.
Here is the Lewis structrue for ClO2-
from class on Monday, November 27, 2000.
Here is the Lewis structrue for H2SO4
from class on Monday, November 27, 2000.
Here is the Lewis structrue for C2H6
from class on Monday, November 27, 2000.
Here is the Lewis structrue for CO2
and an introduction to formal charge from class on Wednesday, November
29, 2000.
Here is how use formal charge to arrive
at a better Lewis structure for H2SO4 from class
on Wednesday, November 29, 2000.
Here is Lewis structure for C2H4
and C2H2
from class on Wednesday, November 29, 2000.
Here is Lewis structure for NO3-
and an introduction to resonance structures from class on Wednesday,
November 29, 2000.
Here is some discussion and help on
PS15.6 from the Help Session on Monday, November 27, 2000. (Note: In this
discussion I cover part i and j and discuss multiple bonds in Lewis structures.)
Problem Set #16 (Due Friday, December 8, 2000 at 5:00
pm (1:30 pm) and 7:00 pm (3:30 pm)) : Answers : Grading
Info
Here is some discussion on lone pairs
of electrons and bond angles which will help on PS16.3a from the Lecture
on Friday, December 8, 2000.
Here is some discussion and help on
PS16.7 covering the notation in the problem and how to determine bond angles
and the number of sigma and pi-bonds in a sample compound from the Lecture
on Friday, December 8, 2000.
Problem
Set #17 (Wednesday, December 13, 2000 by 5:00 pm) : Answers : Grading Info
Note: Sometimes even I get the wrong answer on a problem. If
you do not agree with any of my answers please contact me and we
can discuss the discrepancy.
We are going to try some inclass problem sets during the
discussion portion of lab class. The intent is to give you time
to work together in small groups on problems like the problems on
the problem set. Ask your TA questions when you encounter
roadblocks. Hopefully the practice will make the problem set
questions easier.
InClass Exercise #1 for the week of August 21, 2000:
Answers
InClass Exercise #2 for the week of August 28, 2000:
Answers: Comments
InClass Exercise #3 for the week of October 2, 2000:
Answers
InClass Exercise #4 for the week of November 20, 2000:
Answers
Here are some drill-and-practice
problems to test your skills.
Suggested problems from our textbook
-
Chapter 1: 4, 6, 8, 19, 21, 26, 28, 30, 34, 36, 38, 40, 42,
44, 52, 54, 56, 58, 60, 62, 64, 66, 68, 70, 74, 79, 88.
-
Chapter 2: 1, 4, 14, 18, 20, 22, 27, 29, 34, 37, 39, 41,
43, 45, 47, 58, 61, 64, 68, 70, 72, 74, 76, 78, 82, 84, 86, 88, 90, 92,
94, 96, 98, 100, 102, 104, 106, 108, 132, 139, 142.
-
Chapter 3: 2, 8, 10, 12, 14, 16, 18, 20, 23, 25, 31, 33,
35, 37, 39, 41, 44, 50, 51, 53, 55, 59, 61, 63, 65, 67, 69, 73, 75, 77,
79, 81, 83, 85, 92, 94, 96, 98, 100, 102, 105, 121, 123, 131, 132.
-
Chapter 4: 10, 14, 16, 18, 20, 26, 34, 36, 38, 40, 42, 44,
46, 50, 86, 88, 90, 92 (skip the redox rxn identification), 94, and 96 (combination
is same as our formation rxn).
-
Chapter 5: 6, 8, 18, 20, 22, 24, 26, 28, 30, 33, 35, 38,
40, 42, 44, 48, 51, 53, 55, 57, 66, 67, 71, 73, and 77.
-
Chapter 6: 8, 17, 19, 22, 24, 26, 31, 35, 37, 39, 41, 43,
48, 49, 50, 52, 54, 58, 62, 63, 65, 67, 70, 72, 73, 75, 77, 80 and 84.
-
Chapter 7: 2, 5, 7, 9, 11, 13, 16, 20, 22, 23, 25, 27, 29,
31, 37, 47, 48, 49, 51, 53, 55, 57, 59, 75.
-
Chapter 8: 9, 11, 13, 16, 18, 20, 21, 23, 25, 27, 29, 31,
33, 35, 37, 39, 41, 46, 48, 50, 53, 55, 57, 59, 74, 76, 78, 80, 82, 86.
-
Chapter 9: 10, 12, 14, 17, 20, 22, 24, 26, 28, 30, 33, 35,
39, 41, 43, 45, 48, 50, 56, 67
-
Chapter 10:1, 2, 5 - 22, 25, 30, 32, 34, 39, 43 - 58, 61,
64, 66, 68.
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