In Chapter 10 we will focus on gases and their properties. As
an introduction to gases we can look at the periodic table and
recall those elements which are found in the gas phase under
standard conditions.
If we look at a periodic table which identifies the phase of
each element at standard conditions we see that the dominate
phase is solid followed by the gas phase and finally the liquid
phase.
The elements which are gases include, hydrogen, helium,
oxygen, nitrogen, fluorine, chlorine and all the noble gases.
We'll take a few moments to look at several of these gaseous
elements. I'll expect you to know the standard state phase of
every element in the periodic table. Now you might be thinking,
holy cow, are you nuts, but remember 2 of the elements are
liquids and 10 of the elements are gases. So it is not so bad.
Also I'll expect you to know the color of each of the gaseous
elements.
Hydrogen is the most abundant element in the universe.
Hydrogen is a colorless, odorless, tasteless gas. If boils at
-252.8°ree;C and freezes at -259.1°ree;C. Hydrogen is obtained from
water using a variety of chemical rxns.
Helium was the 1st noble gas to be discovered. It was
identified on the sun before it was found on the earth. It
discovery was made by a French astronomer Pierre Jules Casar
Janssen in 1868. Helium is colorless, odorless, tasteless gas at
room temperature. It boils as -268.6 °ree;C. It is the only element
that cannot be converted to a solid by cooling alone. (Note later
the pressure must be increased to 26 atmospheres before helium
solidifies at -272 °ree;C.)
Oxygen, O2, is the most abundant element in the earths
crust. O2 was discovered in the late 18th century by the English
chemist Joseph Priestly. A colorless gas, at room temperature it
condenses to a blue liquid at -183°ree;C and freezes to a pale blue
solid at -218°ree;C. Obtained by the liquification of air.
Although nitrogen is the most abundant element in the
atmosphere it is not particularly abundant on earth because there
are few compounds containing nitrogen which are solids. Nitrogen
is a colorless, odorless, tasteless gas. It boils at -196°ree;C and
freezes at -210°ree;C. It is obtained from inpirification of air.
Fluorine is a pale yellow gas with a boiling point of
188 °ree;C. It freezes at 218 °ree;C. Fluorine is an
extremely reactive gas and very difficult to work with in its a
elemental state. I cannot show you a sample of fluorine beause of
its reactivity. In fact, it is so reactive it even forms
compounds with noble gas elements like xenon. We will talk about
this interesting behavior later. Fluorine is commonly found in
many minerals. (fluorspar, CaF2; cryolite, Na3AlF6 and
fluorapatite, Ca3(PO4)3F).
Argon was identified by the physicist Lord Rayleigh
and Sir William Ramsay. Their individual experiments identified
the colorless, odorless, tasteless gas in 1894. It was the first
nobel gas isolated on earth.
Later in 1898 Ramsay and an assistant Morris Travers isolated
neon, from a sample of impure oxygen. They were also able to show
that air contained two other element which they identified
Krypton and Xenon.
Radon is obtained as a disintegration product of
radium. It is a radioactive gas. Radon-222 decays by alpha
particle emission to a variety of solid radioisatopes. Two of
these isotopes are polorium-218 and polorium-214 which are also
alpha emitted. As solids these remain in the lung. Radon, as a
gas, is inhaled and then exhaled. Range of an alpha particle is
very short.
Chlorine is a pale greenishyellow gas, with a
boiling point of 101 °ree;C and a melting point of 34
°ree;C. Chlorine is the most important of the halogens. (Look up
some hazardous info on chlorine.)
Under appropriate conditions substances which are normally
liquids or solids can exist in the gas phase. In such cases the
gaseous phase of the substance is called vapor. For example, one
of the two elements which exists as a liquid is bromine (show
the periodic table). Here is a picture of bromine. Do you see
the liquid phase of bromine? Do you see the vapor phase?