We'll begin this Chapter with a list of Objectives. This is a list of what skills you must have when we have completed this chapter.
- define the terms thermodynamics and thermochemistry.
- describe the kinetic and potential energy and calculate the amount of kinetic energy of a moving object.
- state the unit conversion relating joules and calories.
- describe the difference between temperature and heat.
- distinguish between the system and the surrounding in a chemical process.
- define the terms exothermic and endothermic as they apply to chemical reactions.
- define the terms specific heat and heat capacity and use both concepts to calculate heat flow.
- calculate heat flow in a coffee-cup calorimetry experiment.
- calculate heat flow in a bomb calorimeter experiment.
- state the first law of thermodynamics.
- write the mathematical equation defining the internal energy change in a chemical reaction.
- calculate the internal energy change for a chemical process in terms of heat flow and work.
- write the mathematical equation for heat flow in chemical reactions at constant volume and constant pressure.
- define the term enthalpy (H) and distinguish it from internal energy (E).
- list the important characteristics of enthalpy of a chemical reaction.
- describe and recognize state functions.
- calculate the enthalpy change in a chemical reaction using Hess's Law.
- define the term standard state as it is applied to an element or compound.
- write a chemical equation describing the formation of any compound and look up its heat of formation in table of standard heats of formation.
- calculate the enthalpy change in any chemical reaction using standard enthalpies of formation.
- calculate the fuel value (heat of combustion) of a chemical compound using standard enthalpies of formation.