Ester Functional Group

Esters are very similar to carboxylic acids. The carboxylic acid functional group is shown along with the ester functional group.

Functional Group

Lewis Structure

Electron-dot Structure

Condensed Formula

Carboxylic acid

-COOH

Ester

-COO-

The ester functional group does not look much differet next to the carboxylic acid functional group. In fact you might notice the only diference is the hydrogen atom, present in the carboxylic acid absent in the ester. This IS the key difference. So what does the ester have in place of that hydrogen atom? Ester have carbon atoms in place of that hydrogen.

The simplest ester is H3CCOOCH3. The structure of this compound is shown below.

Ball-and-Stick

Lewis Structure

Electron-dot Structure

So esters have a carbon atom attached to the oxygen that a hydrogen atom is attached to in a carboxylic acid.

So for both the ester and the carboxylic acid we look for a carbon atom with one double bonded oxygen and one single bonded oxygen. The difference between the ester and the carboxylic acid is whether the single bonded oxygen has a hydrogen atom bonded to it or a carbon atom.

Esters have very pleasant odors. The odors of the three esters below are very familiar to all of us.

Ball-and-Stick

Lewis Structure

Electron-dot Structure

Odor

Banana

pineapple

 

 

rose

Return to man functional group page.